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Alkyl polyglycosides (APGs) are a class of non-ionic surfactants widely used in a variety of cosmetic, household, and industrial applications. Biodegradable and plant-derived from sugars, these surfactants are usually derivatives of glucose and fatty alcohols . [ 1 ]
Surfactant molecules have either one tail or two; those with two tails are said to be double-chained. [4] Surfactant classification according to the composition of their head: non-ionic, anionic, cationic, amphoteric. Most commonly, surfactants are classified according to polar head group. A non-ionic surfactant has no charged groups in its ...
Griffin's method for non-ionic surfactants as described in 1954 works as follows: = / where is the molecular mass of the hydrophilic portion of the molecule, and M is the molecular mass of the whole molecule, giving a result on a scale of 0 to 20. An HLB value of 0 corresponds to a completely lipophilic/hydrophobic molecule, and a value of 20 ...
Polyethylene glycol cetyl ether (polyethylene glycol hexadecyl ether) is a nonionic surfactant produced by the ethoxylation of cetyl alcohol to give a material with the general formula HO(C 2 H 4 O) n C 16 H 33.
Non-ionic surfactants are non-charged and together with anionic surfactants make up the majority of oil-dispersant formulations. [25] The hydrophilic portion of the surfactant contains polar functional groups, such as -OH or -NH. [26] Zwitterionic surfactants are the most expensive, and are used for specific applications. [26]
In ternary systems such as microemulsions, where two immiscible phases (water and ‘oil’) are present with a surfactant, the surfactant molecules may form a monolayer at the interface between the oil and water, with the hydrophobic tails of the surfactant molecules dissolved in the oil phase and the hydrophilic head groups in the aqueous phase.
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