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Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer propylene . Polypropylene belongs to the group of polyolefins and is partially crystalline and non-polar .
Polypropylene sheets are used for stationery folders and packaging and clear storage bins. Polypropylene is defined by the recyclable plastic number 5. Although relatively inert, it is vulnerable to ultraviolet radiation and can degrade considerably in direct sunlight. Polypropylene is not as impact-resistant as the polyethylenes (HDPE, LDPE).
The onset of thermal degradation dictates the maximum temperature at which a polymer can be used. It is an important limitation in how the polymer is manufactured and processed. For instance, polymers become less viscous at higher temperatures which makes injection moulding easier and faster, but thermal degradation places a ceiling temperature ...
The PP and PE components of a blend constitute the "crystalline phase", and the rubber and branched PE chains and PE/PP end groups gives the "amorphous phase". If PP and PE are the dominant component of a TPO blend then the rubber fraction will be dispersed into a continuous matrix of "crystalline" polypropylene.
For example, atactic polypropylene is usually amorphous and transparent while syndiotactic polypropylene, which has crystallinity ~50%, is opaque. [30] Crystallinity also affects dyeing of polymers: crystalline polymers are more difficult to stain than amorphous ones because the dye molecules penetrate through amorphous regions with greater ease.
Left: individual linear polymer chains Right: Polymer chains which have been cross linked to give a rigid 3D thermoset polymer. In materials science, a thermosetting polymer, often called a thermoset, is a polymer that is obtained by irreversibly hardening ("curing") a soft solid or viscous liquid prepolymer (). [1]
The heat deflection temperature or heat distortion temperature (HDT, HDTUL, or DTUL) is the temperature at which a polymer or plastic sample deforms under a specified load. [1] This property of a given plastic material is applied in many aspects of product design, engineering and manufacture of products using thermoplastic components.
Thermal depolymerization (TDP) is the process of converting a polymer into a monomer or a mixture of monomers, [1] by predominantly thermal means. It may be catalyzed or un-catalyzed and is distinct from other forms of depolymerization which may rely on the use of chemicals or biological action.
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