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Common absorption refrigerators use a refrigerant with a very low boiling point (less than −18 °C (0 °F)) just like compressor refrigerators.Compression refrigerators typically use an HCFC or HFC, while absorption refrigerators typically use ammonia or water and need at least a second fluid able to absorb the coolant, the absorbent, respectively water (for ammonia) or brine (for water).
The refrigerants used in absorption systems are ammonia, water, or methanol, etc, which all experience phase changes between the vapor and liquid states - the same as in vapor compression refrigeration; while the adsorbent is a solid, such as silica gel, activated carbon, or zeolite. [1]
The absorption cycle is similar to the compression cycle, but depends on the partial pressure of the refrigerant vapor. In the absorption system, the compressor is replaced by an absorber and a generator. The absorber dissolves the refrigerant in a suitable liquid (dilute solution) and therefore the dilute solution becomes a strong solution.
The Einstein–Szilard or Einstein refrigerator is an absorption refrigerator which has no moving parts, operates at constant pressure, and requires only a heat source to operate. It was jointly invented in 1926 by Albert Einstein and his former student Leó Szilárd , who patented it in the U.S. on November 11, 1930 ( U.S. patent 1,781,541 ).
Some work is needed by the liquid pump but, for a given quantity of refrigerant, it is much smaller than needed by the compressor in the vapor compression cycle. In an absorption refrigerator, a suitable combination of refrigerant and absorbent is used.
In cheaper and/or older models, a defrost cycle is controlled via a mechanical timer. This timer is set to shut off the compressor and fan and energize a heating element located near or around the evaporator for about 15 to 30 minutes at every 6 to 12 hours. This melts any frost or ice build-up and allows the refrigerator to work normally once ...
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