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This lists the character tables for the more common molecular point groups used in the study of molecular symmetry. These tables are based on the group-theoretical treatment of the symmetry operations present in common molecules, and are useful in molecular spectroscopy and quantum chemistry. Information regarding the use of the tables, as well ...
The irreducible complex characters of a finite group form a character table which encodes much useful information about the group G in a concise form. Each row is labelled by an irreducible character and the entries in the row are the values of that character on any representative of the respective conjugacy class of G (because characters are class functions).
In Schoenflies notation, point groups are denoted by a letter symbol with a subscript. The symbols used in crystallography mean the following: C n (for cyclic) indicates that the group has an n-fold rotation axis.
In Hermann–Mauguin notation, space groups are named by a symbol combining the point group identifier with the uppercase letters describing the lattice type.Translations within the lattice in the form of screw axes and glide planes are also noted, giving a complete crystallographic space group.
The 2p x orbital of oxygen has B 1 symmetry as in the fourth row of the character table above, with x in the sixth column). It is oriented perpendicular to the plane of the molecule and switches sign with a C 2 and a σ v '(yz) operation, but remains unchanged with the other two operations (obviously, the character for the identity operation is ...
In other cases there is no point around which the point group applies. The notation is somewhat ambiguous, without a table giving more information. For example, space groups I23 and I2 1 3 (nos. 197 and 199) both contain two-fold rotational axes as well as two-fold screw axes. In the first, the two-fold axes intersect the three-fold axes ...
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