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In stereochemistry, enantiomeric excess (ee) is a measurement of purity used for chiral substances. It reflects the degree to which a sample contains one enantiomer in greater amounts than the other.
In electrochemistry, the electrochemical potential of electrons (or any other species) is the total potential, including both the (internal, nonelectrical) chemical potential and the electric potential, and is by definition constant across a device in equilibrium, whereas the chemical potential of electrons is equal to the electrochemical ...
Cyclic voltammetry (CV) has become an important and widely used electroanalytical technique in many areas of chemistry. It is often used to study a variety of redox processes, to determine the stability of reaction products, the presence of intermediates in redox reactions, [10] electron transfer kinetics, [11] and the reversibility of a ...
The maximum variance of this distribution is 0.25, which occurs when the true parameter is p = 0.5. In practical applications, where the true parameter p is unknown, the maximum variance is often employed for sample size assessments. If a reasonable estimate for p is known the quantity () may be used in place of 0.25.
A test statistic shares some of the same qualities of a descriptive statistic, and many statistics can be used as both test statistics and descriptive statistics. However, a test statistic is specifically intended for use in statistical testing, whereas the main quality of a descriptive statistic is that it is easily interpretable. Some ...
Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
The silver concentration in the test sample is the x-intercept of the plot. The dilution factor is multiplied by this initial concentration to determine the original concentration. Matrix effects occur even with methods such as plasma spectrometry , which have a reputation for being relatively free from interferences.
The system of this measurement is usually the same as that of standard voltammetry.The potential between the working electrode and the reference electrode is changed as a pulse from an initial potential to an interlevel potential and remains at the interlevel potential for about 5 to 100 milliseconds; then it changes to the final potential, which is different from the initial potential.