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The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas. The rule is especially applicable to carbon, nitrogen, oxygen, and the halogens; although more generally the ...
Octet rule is used with Lewis structures for main group elements, especially the lighter ones such as carbon, nitrogen, and oxygen, 18-electron rule [2] in inorganic chemistry and organometallic chemistry of transition metals, Hückel's rule for the π-electrons of aromatic compounds,
Most homoleptic organo-main group compounds adopt a characteristic oxidation state: RLi, R 2 Be, R 3 B/R 3 Al, R 4 Si, R 3 P, R 2 S. Members where the simplest stoichiometry violates the octet rule often aggregate by formation of bridging alkyl groups. When the alkyl group bridges two main group elements, the bonding is called three-center two ...
Under the framework of valence bond theory, resonance is an extension of the idea that the bonding in a chemical species can be described by a Lewis structure. For many chemical species, a single Lewis structure, consisting of atoms obeying the octet rule, possibly bearing formal charges, and connected by bonds of positive integer order, is sufficient for describing the chemical bonding and ...
Satisfy the octet rule. Both oxygen atoms currently have 8 electrons assigned to them. The nitrogen atom has only 6 electrons assigned to it. One of the lone pairs on an oxygen atom must form a double bond, but either atom will work equally well. Therefore, there is a resonance structure. Tie up loose ends.
A double bond between two given atoms consists of one σ and one π bond, and a triple bond is one σ and two π bonds. [8] Covalent bonds are also affected by the electronegativity of the connected atoms which determines the chemical polarity of the bond. Two atoms with equal electronegativity will make nonpolar covalent bonds such as H–H.
Alternatively, electron-deficiency describes molecules or ions that function as electron acceptors. Such electron-deficient species obey the octet rule, but they have (usually mild) oxidizing properties. [4] 1,3,5-Trinitrobenzene and related polynitrated aromatic compounds are often described as electron-deficient. [5]
Additional modifications to the octet rule have been attempted to involve ionic characteristics in hypervalent bonding. As one of these modifications, in 1951, the concept of the 3-center 4-electron (3c-4e) bond , which described hypervalent bonding with a qualitative molecular orbital , was proposed.