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A substance is pyrophoric (from Ancient Greek: πυροφόρος, pyrophoros, 'fire-bearing') if it ignites spontaneously in air at or below 54 °C (129 °F) (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). [1] Examples are organolithium compounds and triethylborane.
It is a colorless, pyrophoric gas with a sharp, repulsive, pungent smell, somewhat similar to that of acetic acid. [6] Silane is of practical interest as a precursor to elemental silicon . Silanes with alkyl groups are effective water repellents for mineral surfaces such as concrete and masonry.
Germane is a highly flammable, potentially pyrophoric, [11] and a highly toxic gas. In 1970, the American Conference of Governmental Industrial Hygienists (ACGIH) published the latest changes and set the occupational exposure threshold limit value at 0.2 ppm for an 8-hour time weighted average. [ 12 ]
White phosphorus is rather acutely toxic, with a lethal dose of 50-100 mg (1 mg/kg body weight). Its mode of action is thought to involve its reducing properties. It is metabolized to phosphate, which is not toxic. [10] White phosphorus is used as a weapon because it is pyrophoric. For the same reasons, it is dangerous to handle.
A steel bottle containing MgCp 2 (magnesium bis-cyclopentadienyl), which, like several other organometallic compounds, is pyrophoric in air.. Organometallic compounds are distinguished by the prefix "organo-" (e.g., organopalladium compounds), and include all compounds which contain a bond between a metal atom and a carbon atom of an organyl group. [2]
Medical biophysics is a field closely related to physiology. It explains various aspects and systems of the body from a physical and mathematical perspective. Examples are fluid dynamics of blood flow, gas physics of respiration, radiation in diagnostics
For example: At 10 meters sea water (msw) the partial pressure of nitrogen in air will be 1.58 bar. [3] The inert gases from the breathing gas in the lungs diffuse into blood in the alveolar capillaries ("move down the pressure gradient") and are distributed around the body by the systemic circulation in the process known as perfusion. [3]
Diborane is a pyrophoric gas. Commercially available adducts are typically used instead, at least for applications in organic chemistry. These adducts include borane-tetrahydrofuran (borane-THF) and borane-dimethylsulfide. [16] The toxic effects of diborane are mitigated because the compound is so unstable in air.