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In organic chemistry, a carbonyl group is a functional group with the formula C=O, composed of a carbon atom double-bonded to an oxygen atom, and it is divalent at the C atom. It is common to several classes of organic compounds (such as aldehydes, ketones and carboxylic acid), as part of many larger functional groups. A compound containing a ...
Most metal carbonyl complexes contain a mixture of ligands. Examples include the historically important IrCl(CO)(P(C 6 H 5) 3) 2 and the antiknock agent (CH 3 C 5 H 4)Mn(CO) 3. The parent compounds for many of these mixed ligand complexes are the binary carbonyls, those species of the formula [M x (CO) n] z, many of which are
Urea, also called carbamide (because it is a diamide of carbonic acid), is an organic compound with chemical formula CO(NH 2) 2. This amide has two amino groups (– NH 2) joined by a carbonyl functional group (–C(=O)–). It is thus the simplest amide of carbamic acid. [6]
The carbonyl group is polar because the electronegativity of the oxygen is greater than that for carbon. Thus, ketones are nucleophilic at oxygen and electrophilic at carbon. Because the carbonyl group interacts with water by hydrogen bonding, ketones are typically more soluble in water than the related methylene compounds. Ketones are hydrogen ...
The compound's most noteworthy structural feature is the long carbon-carbon bond of 1.54 Å, which indicates the absence of pi-bonding between the two carbonyl centers.The PhCO centers are planar, but the pair of benzoyl groups are twisted with respect to the other with a dihedral angle of 117°. [5]
Dimanganese decacarbonyl, [3] which has the chemical formula Mn 2 (CO) 10, is a binary bimetallic carbonyl complex centered around the first row transition metal manganese.The first reported synthesis of Mn 2 (CO) 10 was in 1954 at Linde Air Products Company and was performed by Brimm, Lynch, and Sesny. [4]
A titanium compound, Tebbe's reagent, is useful for the synthesis of methylene compounds; in this case, even esters and amides react. A pair of ketones or aldehydes can be deoxygenated to generate an alkene. Symmetrical alkenes can be prepared from a single aldehyde or ketone coupling with itself, using titanium metal reduction (the McMurry ...
General formula of a thioketone. In organic chemistry, thioketones (from Ancient Greek θεῖον (theion) 'sulfur'; [1] also known as thiones or thiocarbonyls) are organosulfur compounds related to conventional ketones in which the oxygen has been replaced by a sulfur. [2]