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Caesium-137 (137 55 Cs), cesium-137 (US), [7] or radiocaesium, is a radioactive isotope of caesium that is formed as one of the more common fission products by the nuclear fission of uranium-235 and other fissionable isotopes in nuclear reactors and nuclear weapons.
Group 9, by modern IUPAC numbering, [1] is a group (column) of chemical elements in the d-block of the periodic table. Members of Group 9 include cobalt (Co), rhodium (Rh), iridium (Ir) and meitnerium (Mt). [ 2 ]
Iridium-192 is a very strong gamma ray emitter, with a gamma dose-constant of approximately 1.54 μSv·h −1 ·MBq −1 at 30 cm, and a specific activity of 341 TBq·g −1 (9.22 kCi·g −1). [ 14 ] [ 15 ] There are seven principal energy packets produced during its disintegration process ranging from just over 0.2 to about 0.6 MeV .
These elements are all transition metals in the d-block (groups 8, 9, and 10, periods 5 and 6). [1] The six platinum-group metals are ruthenium, rhodium, palladium, osmium, iridium, and platinum. They have similar physical and chemical properties, and tend to occur together in the same mineral deposits. [2]
Iridium compounds are used as catalysts in the Cativa process for carbonylation of methanol to produce acetic acid. [92] [93] Iridium complexes are often active for asymmetric hydrogenation both by traditional hydrogenation. [94] and transfer hydrogenation. [95] This property is the basis of the industrial route to the chiral herbicide (S ...
Iridium-192 is a very strong gamma ray emitter, with a gamma dose-constant of approximately 1.54 μSv·h −1 ·MBq −1 at 30 cm, and a specific activity of 341 TBq·g −1 (9.22 kCi·g −1). [ 4 ] [ 5 ] There are seven principal energy packets produced during its disintegration process ranging from just over 0.2 to about 0.6 MeV .
It is followed by caesium, iridium and palladium by mass and iridium, gold and platinum by volume. Carbon in the form of diamond can be more expensive than rhodium. Per-kilogram prices of some synthetic radioisotopes range to trillions of dollars.
Organoiridium compounds share many characteristics with those of rhodium, but less so with cobalt. Iridium can exist in oxidation states of -III to +V, but iridium(I) and iridium(III) are the more common. iridium(I) compounds (d 8 configuration) usually occur with square planar or trigonal bipyramidal geometries, whereas iridium(III) compounds (d 6 configuration) typically have an octahedral ...
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