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In thermodynamics, the compressibility factor (Z), also known as the compression factor or the gas deviation factor, describes the deviation of a real gas from ideal gas behaviour. It is simply defined as the ratio of the molar volume of a gas to the molar volume of an ideal gas at the same temperature and pressure .
The compressibility factor is defined as = where p is the pressure of the gas, T is its temperature, and is its molar volume, all measured independently of one another. In the case of an ideal gas, the compressibility factor Z is equal to unity, and the familiar ideal gas law is recovered:
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
compressibility effects; variable specific heat capacity; van der Waals forces; non-equilibrium thermodynamic effects; issues with molecular dissociation and elementary reactions with variable composition; For most applications, such a detailed analysis is unnecessary, and the ideal gas approximation can be used with reasonable accuracy.
battery, Hydrogen closed cycle H fuel cell [17] 1.62: Hydrazine decomposition (as monopropellant) 1.6: 1.6: Ammonium nitrate decomposition (as monopropellant) 1.4: 2.5: Thermal Energy Capacity of Molten Salt: 1 [citation needed] 98% [18] Molecular spring approximate [citation needed] 1: battery, Lithium–Manganese [19] [20] 0.83-1.01: 1.98-2. ...
Table data obtained from CRC Handbook of Chemistry and Physics 44th ed. Annotation "(s)" indicates equilibrium temperature of vapor over solid. Otherwise temperature is equilibrium of vapor over liquid.
The compressibility factor is a dimensionless quantity which is equal to 1 for ideal gases and deviates from unity for increasing levels of non-ideality. [ 9 ] Several non-ideal models exist, from the simplest cubic equations of state (such as the Van der Waals [ 4 ] [ 10 ] and the Peng-Robinson [ 11 ] models) up to complex multi-parameter ones ...
F pv: super compressibility factor (often omitted or shown as equaling 1) Example: How many standard cubic feet are in 1 cubic foot of gas at 80 °F and gauge pressure 50 psi? (assuming that there is 13.6 psi atmospheric pressure and ignoring super compressibility)