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Often, an equivalent circuit is sought that simplifies calculation, and more broadly, that is a simplest form of a more complex circuit in order to aid analysis. [1] In its most common form, an equivalent circuit is made up of linear, passive elements. However, more complex equivalent circuits are used that approximate the nonlinear behavior of ...
For Faraday's first law, M, F, v are constants; thus, the larger the value of Q, the larger m will be. For Faraday's second law, Q, F, v are constants; thus, the larger the value of (equivalent weight), the larger m will be. In the simple case of constant-current electrolysis, Q = It, leading to
where: k 1 is the rate coefficient for the reaction that consumes A and B; k −1 is the rate coefficient for the backwards reaction, which consumes P and Q and produces A and B. The constants k 1 and k −1 are related to the equilibrium coefficient for the reaction (K) by the following relationship (set v=0 in balance):
The current entering any junction is equal to the current leaving that junction. i 2 + i 3 = i 1 + i 4. This law, also called Kirchhoff's first law, or Kirchhoff's junction rule, states that, for any node (junction) in an electrical circuit, the sum of currents flowing into that node is equal to the sum of currents flowing out of that node; or equivalently:
As an example, consider the gas-phase reaction NO 2 + CO → NO + CO 2.If this reaction occurred in a single step, its reaction rate (r) would be proportional to the rate of collisions between NO 2 and CO molecules: r = k[NO 2][CO], where k is the reaction rate constant, and square brackets indicate a molar concentration.
Rate 1 is the rate of effusion for the first gas. (volume or number of moles per unit time). Rate 2 is the rate of effusion for the second gas. M 1 is the molar mass of gas 1 M 2 is the molar mass of gas 2. Graham's law states that the rate of diffusion or of effusion of a gas is inversely proportional to the square root of its molecular weight.
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
Seventh grade (also 7th Grade or Grade 7) is the seventh year of formal or compulsory education. The seventh grade is typically the first or second year of middle school. In the United States, kids in seventh grade are usually around 12–13 years old. Different terms and numbers are used in other parts of the world.