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The Union Carbide (UCC) process, also known as low-pressure oxo process (LPO), relies on a rhodium catalyst dissolved in high-boiling thick oil, a higher molecular weight condensation product of the primary aldehydes, for the hydroformylation of propene. The reaction mixture is separated in a falling film evaporator from volatile components.
Typical catalysts are platinum, and redox-active oxides of iron, vanadium, and molybdenum. In many cases, catalysts are modified with a host of additives or promoters that enhance rates or selectivities. Important homogeneous catalysts for the oxidation of organic compounds are carboxylates of cobalt, iron, and manganese
The use of sparteine as a ligand (Figure 2, A) [33] favors nucleopalladation at the terminal carbon to minimize steric interaction between the palladium complex and substrate. The Quinox-ligated palladium catalyst is used to favor ketone formation when substrate contains a directing group (Figure 2, B). [34]
Fluid catalytic cracking is a commonly used process, and a modern oil refinery will typically include a cat cracker, particularly at refineries in the US, due to the high demand for gasoline. [10] [11] [12] The process was first used around 1942 and employs a powdered catalyst. During WWII, the Allied Forces had plentiful supplies of the ...
Steam cracker process diagram Gibbs free energy per carbon atom. This shows that at high temperature, hexane can split into ethane and ethylene ("Ethen"), and ethane can split into ethylene and hydrogen. But ethylene can decompose into methane and carbon if given too much time, and all the hydrocarbons can decompose into carbon and hydrogen.
The bottom oil from the slurry settler contains most of the slurry oil catalyst particles and is recycled back into the catalyst riser by combining it with the FCC feedstock oil. The clarified slurry oil or decant oil is withdrawn from the top of slurry settler for use elsewhere in the refinery, as a heavy fuel oil blending component, or as ...
Hydrothermal liquefaction (HTL) is a thermal depolymerization process used to convert wet biomass, and other macromolecules, into crude-like oil under moderate temperature and high pressure. [1] The crude-like oil has high energy density with a lower heating value of 33.8-36.9 MJ/kg and 5-20 wt% oxygen and renewable chemicals.
Oxo alcohols are alcohols that are prepared by adding carbon monoxide (CO) and hydrogen (usually combined as synthesis gas) to an olefin to obtain an aldehyde using the hydroformylation reaction and then hydrogenating the aldehyde to obtain the alcohol. [1]