Search results
Results from the WOW.Com Content Network
The integral heat of dissolution is defined as a process of obtaining a certain amount of solution with a final concentration. The enthalpy change in this process, normalized by the mole number of solute, is evaluated as the molar integral heat of dissolution. Mathematically, the molar integral heat of dissolution is denoted as:
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
The heat of dilution can be defined from two perspectives: the differential heat and the integral heat. The differential heat of dilution is viewed on a micro scale, which is associated with the process in which a small amount of solvent is added to a large quantity of solution. The molar differential heat of dilution is thus defined as the enthalpy
Potassium chloride (KCl, or potassium salt) is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a salt-like taste. Potassium chloride can be obtained from ancient dried lake deposits. [7]
Hess's law states that the sum of the energy changes of all thermochemical equations included in an overall reaction is equal to the overall energy change. Since Δ H {\displaystyle \Delta H} is a state function and is not dependent on how reactants become products as a result, steps (in the form of several thermochemical equations) can be used ...
Thus, it reacts with glucose to give carbon dioxide, water molecules and potassium chloride: 3 KClO 4 + C 6 H 12 O 6 → 6 CO 2 + 6 H 2 O + 3 KCl. The conversion of solid glucose into hot gaseous CO 2 is the basis of the explosive force of this and other such mixtures. With sugar, KClO 4 yields a low explosive, provided a necessary confinement.
Potassium hypochlorite is produced by the disproportionation reaction of chlorine with a solution of potassium hydroxide: [2] Cl 2 + 2 KOH → KCl + KOCl + H 2 O. This is the traditional method, first used by Claude Louis Berthollet in 1789. [3] Another production method is electrolysis of potassium chloride solution.
Potassium chlorate can be produced in small amounts by disproportionation in a sodium hypochlorite solution followed by metathesis reaction with potassium chloride: [7] 3 NaOCl → 2 NaCl + NaClO 3 KCl + NaClO 3 → NaCl + KClO 3. It can also be produced by passing chlorine gas into a hot solution of caustic potash: [8] 3 Cl 2 + 6 KOH → KClO ...