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An electron donating group (EDG) or electron releasing group (ERG, Z in structural formulas) is an atom or functional group that donates some of its electron density into a conjugated π system via resonance (mesomerism) or inductive effects (or induction)—called +M or +I effects, respectively—thus making the π system more nucleophilic.
An electron-withdrawing group (EWG) is a group or atom that has the ability to draw electron density toward itself and away from other adjacent atoms. [1] This electron density transfer is often achieved by resonance or inductive effects.
Like the periodic table, the list below organizes the elements by the number of protons in their atoms; it can also be organized by other properties, such as atomic weight, density, and electronegativity. For more detailed information about the origins of element names, see List of chemical element name etymologies.
Delocalizing the radical ion stabilizes the transition state structure. As a result, the energy of activation decreases, enhancing the rate of the overall reaction. According to the captodative effect, the rate of a reaction is the greatest when both the EDG and EWG are able to delocalize the radical ion in the transition state structure. [7]
The currently accepted names and symbols of the chemical elements are determined by the International Union of Pure and Applied Chemistry (IUPAC), usually following recommendations by the recognized discoverers of each element. However, the names of several elements have been the subject of controversies until IUPAC established an official name.
Periodic tables usually at least show the elements' symbols; many also provide supplementary information about the elements, either via colour-coding or as data in the cells. The above table shows the names and atomic numbers of the elements, and also their blocks, natural occurrences and standard atomic weights. For the short-lived elements ...
Ruthenium is from the Latin name for the region including Belarus, Ukraine, and Russia. [29] Lutetium is named after Lutetia, the Latin name for Paris. Copper's name comes from an Old English word derived from the Latin name for the island of Cyprus. [30] The names of both magnesium and manganese derive from the Greek region of Magnesia. [31]
Names of oxyanions should in general follow the names in Table X of the IUPAC 2005 Red Book. [2] Exceptions can be made if an alternate name is much more common in the literature, e.g. xenate rather than xenonate (don't generalise this to radon though, as it would create an ambiguity between radon and radium).