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The Hall–Héroult process is the major industrial process for smelting aluminium. It involves dissolving aluminium oxide (alumina) (obtained most often from bauxite , aluminium 's chief ore, through the Bayer process ) in molten cryolite and electrolyzing the molten salt bath, typically in a purpose-built cell.
Efforts to find industrial use for spent anodes have led to proposals to use the anodes as a cost-effective alternative for coke in small-scale foundries that lack a ready supply of coke, and cannot afford modern electric furnaces.
The Hall-Héroult electrolysis process is the major production route for primary aluminium. An electrolytic cell is made of a steel shell with a series of insulating linings of refractory materials. The cell consists of a brick-lined outer steel shell as a container and support. Inside the shell, cathode blocks are cemented together by ramming ...
Hall–Héroult process – Aluminium oxide (Al 2 O 3) is smelted with coke (C) in a high-temperature electrolysis reaction, yielding the desired pure aluminium (Al) and a mixture of CO and CO 2. Al 2 O 3 (s) + 3 C(s) → 2 Al(s) + 3 CO(g)
In 1891 after Cowles began to advertise "pure aluminum" they were sued by the Pittsburgh Reduction Company. The judge announced his decision in January 1893, finding them to be infringing the patent of Hall and having gained knowledge of his process by hiring away a chemist named Hobbs who was the foreman in Pittsburgh.
The Hall-Héroult process for aluminium production from alumina was invented in 1886 by Charles Hall and Paul Héroult. [17] Carl Josef Bayer created a multi-step process to convert raw bauxite into alumina in 1888. [18] As aluminium production rose with the use of these two processes, aluminium recycling grew too.
Charles Martin Hall (December 6, 1863 – December 27, 1914) was an American inventor, businessman, and chemist.He is best known for his invention in 1886 of an inexpensive method for producing aluminum, which became the first metal to attain widespread use since the prehistoric discovery of iron.
[h] Hall co-founded the Pittsburgh Reduction Company in 1888 and initiated production of aluminium. [88] Hall's patent was granted in 1889. [74] [i] In 1889, Hall's production began to use the principle of internal heating. [j] By September 1889, Hall's production grew to 385 pounds (175 kilograms) at a cost of $0.65 per pound. [91]