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Tollens' test for aldehyde: left side positive (silver mirror), right side negative Ball-and-stick model of the diamminesilver(I) complex. Tollens' reagent (chemical formula ()) is a chemical reagent used to distinguish between aldehydes and ketones along with some alpha-hydroxy ketones which can tautomerize into aldehydes.
Tollens' reagent: a chemical test most commonly used to determine whether a known carbonyl-containing compound is an aldehyde or a ketone Triphenylphosphine: used in the synthesis of organic and organometallic compounds
α-hydroxy ketones give positive Tollens' and Fehling's test. Some acyloins rearrange with positions swapped under the influence of base in the Lobry–de Bruyn–van Ekenstein transformation; A similar reaction is the so-called Voigt amination [6] where an acyloin reacts with a primary amine and phosphorus pentoxide to an α-keto amine: [7]
Phloroglucinol is a reagent of the Tollens' test for pentoses. This test relies on reaction of the furfural with phloroglucinol to produce a colored compound with high molar absorptivity. [26] A solution of hydrochloric acid and phloroglucinol is also used for the detection of lignin (Wiesner test).
Formic acid (HCO 2 H) also gives a positive Fehling's test result, as it does with Tollens' (eponymous for Bernhard Christian Gottfried Tollens (1841 – 1918)) test and Benedict's solution also. The positive tests are consistent with it being readily oxidizable to carbon dioxide. The solution cannot differentiate between benzaldehyde and acetone.
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Reducing form of glucose (the aldehyde group is on the far right). A reducing sugar is any sugar that is capable of acting as a reducing agent. [1] In an alkaline solution, a reducing sugar forms some aldehyde or ketone, which allows it to act as a reducing agent, for example in Benedict's reagent.
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