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Ethane-1,2-dithiol, also known as EDT, [1] is a colorless liquid with the formula C 2 H 4 2. It has a very characteristic odor which is compared by many people to rotten cabbage . It is a common building block in organic synthesis and an excellent ligand for metal ions.
In the presence of oxygen, ethane-1,1-dithiol is converted to cis/trans-3,6-dimethyl-1,2,4,5-tetrathiane which has a rubbery aroma. This molecule has a ring with four sulfur atoms and two carbons, two ethane-1,1-dithiol molecules become linked at their sulfur atoms with the loss of hydrogen. [11]
Geminal dithiols have the formula RR'C(SH) 2. They are derived from aldehydes and ketones by the action of hydrogen sulfide. Their stability contrasts with the rarity of geminal diols. Examples include methanedithiol, ethane-1,1-dithiol, and cyclohexane-1,1-dithiol.
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In organosulfur chemistry, a 1,2-dithiole is a type of heterocycle. The parent of this class of compounds is 1,2-dithiacyclopentene. The anticancer drug oltipraz is a dithiole. [1] The drug Oltipraz features a 1,2-dithiole ring.