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[1] [2] [3] It is a measure of the average molecular weight (or chain length) of all the fatty acids present in the sample in form of triglycerides. The higher the saponification value, the lower the fatty acids average length, the lighter the mean molecular weight of triglycerides and vice versa.
HLB scale showing classification of surfactant function. The hydrophilic–lipophilic balance (HLB) of a surfactant is a measure of its degree of hydrophilicity or lipophilicity, determined by calculating percentages of molecular weights for the hydrophilic and lipophilic portions of the surfactant molecule, as described by Griffin in 1949 [1] [2] and 1954. [3]
Some soap-makers leave the glycerol in the soap. Others precipitate the soap by salting it out with sodium chloride. Skeletal formula of stearin, a triglyceride that is converted by saponification with sodium hydroxide into glycerol and sodium stearate. Fat in a corpse converts into adipocere, often called "grave wax".
Detergents. A detergent is a surfactant or a mixture of surfactants with cleansing properties when in dilute solutions. [1] There are a large variety of detergents, a common family being the alkylbenzene sulfonates, which are soap-like compounds that are more soluble in hard water, because the polar sulfonate (of detergents) is less likely than the polar carboxylate (of soap) to bind to ...
Upon introducing surfactants (or any surface active materials) into a system, they will initially partition into the interface, reducing the system free energy by: [citation needed] lowering the energy of the interface (calculated as area times surface tension), and; removing the hydrophobic parts of the surfactant from contact with water.
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A dispersant or a dispersing agent is a substance, typically a surfactant, that is added to a suspension of solid or liquid particles in a liquid (such as a colloid or emulsion) to improve the separation of the particles and to prevent their settling or clumping. [1]
If surfactants are well chosen [2] and the atmospheric humidity and air movements are suitably controlled, a horizontal soap film can last from minutes to hours. In contrast, a vertical soap film is affected by gravity and so the liquid tends to drain, causing the soap film to thin at the top.