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This is a list of unsolved problems in chemistry. Problems in chemistry are considered unsolved when an expert in the field considers it unsolved or when several experts in the field disagree about a solution to a problem.
Iron rusting has a low reaction rate. This process is slow. Wood combustion has a high reaction rate. This process is fast. The reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. [1]
Although Bernoulli deduced that pressure decreases when the flow speed increases, it was Leonhard Euler in 1752 who derived Bernoulli's equation in its usual form. [4] [5] Bernoulli's principle can be derived from the principle of conservation of energy. This states that, in a steady flow, the sum of all forms of energy in a fluid is the same ...
Following the development of the Boltzmann equation, a framework for its use in developing transport equations was developed independently by David Enskog and Sydney Chapman in 1917 and 1916. The framework provided a route to prediction of the transport properties of dilute gases, and became known as Chapman–Enskog theory .
Another example is the unimolecular nucleophilic substitution (S N 1) reaction in organic chemistry, where it is the first, rate-determining step that is unimolecular. A specific case is the basic hydrolysis of tert-butyl bromide (t-C 4 H 9 Br) by aqueous sodium hydroxide. The mechanism has two steps (where R denotes the tert-butyl radical t-C ...
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
For example, if equilibrium is specified by a single chemical equation:, [24] ∑ j = 0 m ν j R j = 0 {\displaystyle \sum _{j=0}^{m}\nu _{j}R_{j}=0} where ν j is the stoichiometric coefficient for the j th molecule (negative for reactants, positive for products) and R j is the symbol for the j th molecule, a properly balanced equation will obey:
A differential equation of motion, usually identified as some physical law (for example, F = ma), and applying definitions of physical quantities, is used to set up an equation to solve a kinematics problem. Solving the differential equation will lead to a general solution with arbitrary constants, the arbitrariness corresponding to a set of ...