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Diffraction from a large three-dimensional periodic structure such as many thousands of atoms in a crystal is called Bragg diffraction. It is similar to what occurs when waves are scattered from a diffraction grating. Bragg diffraction is a consequence of interference between waves reflecting from many different crystal planes.
This equation, Bragg's law, describes the condition on θ for constructive interference. [12] A map of the intensities of the scattered waves as a function of their angle is called a diffraction pattern. Strong intensities known as Bragg peaks are obtained in the diffraction pattern when the scattering angles satisfy Bragg condition.
Figure 1: Selected area diffraction pattern of a twinned austenite crystal in a piece of steel. Electron diffraction is a generic term for phenomena associated with changes in the direction of electron beams due to elastic interactions with atoms. [a] It occurs due to elastic scattering, when there is no change in the energy of the electrons. [1]:
Each dot, called a reflection, forms from the coherent interference of scattered X-rays passing through the crystal. X-ray scattering techniques are a family of non-destructive analytical techniques which reveal information about the crystal structure , chemical composition, and physical properties of materials and thin films.
Each of these beams travels a different route, called a path, and they are recombined before arriving at a detector. The path difference, the difference in the distance traveled by each beam, creates a phase difference between them. It is this introduced phase difference that creates the interference pattern between the initially identical waves.
William Lawrence Bragg proposed a model where the incoming X-rays are scattered specularly (mirror-like) from each plane; from that assumption, X-rays scattered from adjacent planes will combine constructively (constructive interference) when the angle θ between the plane and the X-ray results in a path-length difference that is an integer ...
A blazed diffraction grating reflecting only the green portion of the spectrum from a room's fluorescent lighting. For a diffraction grating, the relationship between the grating spacing (i.e., the distance between adjacent grating grooves or slits), the angle of the wave (light) incidence to the grating, and the diffracted wave from the grating is known as the grating equation.
The first X-ray diffraction experiment was conducted in 1912 by Max von Laue, [7] while electron diffraction was first realized in 1927 in the Davisson–Germer experiment [8] and parallel work by George Paget Thomson and Alexander Reid. [9] These developed into the two main branches of crystallography, X-ray crystallography and electron ...