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Barium carbonate is made commercially from barium sulfide by treatment with sodium carbonate at 60 to 70 °C (soda ash method) or, more commonly carbon dioxide at 40 to 90 °C: In the soda ash process, an aqueous solution of barium sulfide is treated with sodium carbonate: [5] BaS + H 2 O + CO 2 → BaCO 3 + H 2 S
Ba(NO 2) 2: barium nitrite: 13465–94–6 Ba(NO 3) 2: barium nitrate: 10022–31–8 BaN 6: barium azide: 18810–58–7 Ba(NbO 3) 2: barium niobate: 12009–14–2 BaO: barium oxide: 1304–28–5 Ba(OH) 2: barium hydroxide: 17194–00–2 BaO 2: barium peroxide: 1304–29–6 Ba(PO 3) 2: barium metaphosphate: 13466–20–1 Ba(ReO 4) 2 ...
Other compounds of barium find only niche applications, limited by the toxicity of Ba 2+ ions (barium carbonate is a rat poison), which is not a problem for the insoluble BaSO 4. Barium oxide coating on the electrodes of fluorescent lamps facilitates the release of electrons .
Barium carbide can be synthesized as an impure compound by reducing barium carbonate powder with metallic magnesium in the presence of carbon. [3] Barium carbide can also be made by reducing carbon dioxide with hot barium metal at 600°C. [4] These methods are used because of their high yield, and because the carbide is used to make acetylene.
Barium carbonate is often added to maintain anhydrous and acid-free conditions. In the above reaction, while a mixture of isomeric allylic bromide products are possible, only one is created due to the greater stability of the 4-position radical over the methyl-centered radical.
Thorium tetrafluoride (ThF 4, white, m.p. 1068 °C) is most easily produced by reacting various thorium salts, thoria, or thorium hydroxide with hydrogen fluoride: methods that involve steps in the aqueous phase are more difficult because they result in hydroxide and oxide fluorides that have to be reduced with hydrogen fluoride or fluorine gas ...
The eight teams seeded Nos. 5-12 will play in a first round with the better seed hosting the lower seeds either on campus or at other sites designated by the higher-seeded institution (No. 12 at ...
Barium nitrate is manufactured by two processes that start with the main source material for barium, the carbonate. The first involves dissolving barium carbonate in nitric acid, allowing any iron impurities to precipitate, then filtered, evaporated, and crystallized. The second requires combining barium sulfide with nitric acid. [4]