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Sodium nitroprusside (SNP), sold under the brand name Nitropress among others, is a medication used to lower blood pressure. [3] This may be done if the blood pressure is very high and resulting in symptoms, in certain types of heart failure, and during surgery to decrease bleeding. [3]
Sodium nitroprusside, a medicinally significant metal nitrosyl-pentacyanoferrate (Fe-III) compound, used to treat hypertension. [1] Metal nitrosyl complexes are complexes that contain nitric oxide, NO, bonded to a transition metal. [2] Many kinds of nitrosyl complexes are known, which vary both in structure and coligand.
Mössbauer spectrum of sodium nitroprusside, exhibiting quadruple splitting. Quadrupole splitting is an example of a hyperfine interaction found in gamma-ray spectroscopy, in the circumstance where nuclei with a non-radially-symmetric shape (that is, with a spin quantum number greater than 1/2) are found immersed in an external electric field gradient.
A solution of 2% sodium carbonate in water (solution B) [4] Separate storage of the aldehyde and base are necessary to prevent aldol polymerisation of the aldehyde. When exposed to an amine, reaction with acetaldehyde produces the enamine , which subsequently reacts with sodium nitroprusside to the imine .
The French chemist Z. Roussin [5] first prepared this salt while investigating reactions between nitroprusside ion ([Fe(CN) 5 NO] 2−) and sulfur. [6] The salt can be prepared by the reaction of sulfide salts with iron nitrosyl halides: [7] Fe 2 I 2 (NO) 4 + 2Li 2 S → Li 2 Fe 2 S 2 (NO) 4 + 2LiI
Nitrosation is typically performed with nitrous acid, formed from acidification of a sodium nitrite solution. Nitrous acid is unstable, and high yields require a rapid reaction rate. NO + synthon transfer is catalyzed by a strong nucleophile, such as (in order of increasing efficacy) chloride, bromide, thiocyanate, or thiourea.
A nitrovasodilator is a pharmaceutical agent that causes vasodilation (widening of blood vessels) by donation of nitric oxide (NO), [1] and is mostly used for the treatment and prevention of angina pectoris.
Structural formula of nitroso group. In organic chemistry, nitroso refers to a functional group in which the nitric oxide (−N=O) group is attached to an organic moiety.As such, various nitroso groups can be categorized as C-nitroso compounds (e.g., nitrosoalkanes; R−N=O), S-nitroso compounds (nitrosothiols; RS−N=O), N-nitroso compounds (e.g., nitrosamines, RN(−R’)−N=O), and O ...