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The convection–diffusion equation can be derived in a straightforward way [4] from the continuity equation, which states that the rate of change for a scalar quantity in a differential control volume is given by flow and diffusion into and out of that part of the system along with any generation or consumption inside the control volume: + =, where j is the total flux and R is a net ...
The convection–diffusion equation describes the flow of heat, particles, or other physical quantities in situations where there is both diffusion and convection or advection. For information about the equation, its derivation, and its conceptual importance and consequences, see the main article convection–diffusion equation. This article ...
Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
The methods used for solving two dimensional Diffusion problems are similar to those used for one dimensional problems. The general equation for steady diffusion can be easily derived from the general transport equation for property Φ by deleting transient and convective terms [1]
The hybrid difference scheme [1] [2] is a method used in the numerical solution for convection–diffusion problems. It was introduced by Spalding (1970). It is a combination of central difference scheme and upwind difference scheme as it exploits the favorable properties of both of these schemes.
Darken’s equations can be applied to almost any scenario involving the diffusion of two different components that have different diffusion coefficients. This holds true except in situations where there is an accompanying volume change in the material because this violates one of Darken’s critical assumptions that atomic volume is constant.
The Maxwell–Stefan diffusion (or Stefan–Maxwell diffusion) is a model for describing diffusion in multicomponent systems. The equations that describe these transport processes have been developed independently and in parallel by James Clerk Maxwell [ 1 ] for dilute gases and Josef Stefan [ 2 ] for liquids.
Many other convection–diffusion equations describe the conservation and flow of mass and matter in a given system. In chemistry, the calculation of the amount of reactant and products in a chemical reaction, or stoichiometry, is founded on the principle of conservation of mass. The principle implies that during a chemical reaction the total ...