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The equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical equilibrium, a state approached by a dynamic chemical system after sufficient time has elapsed at which its composition has no measurable tendency towards further change.
The weight of the object in the fluid is reduced, because of the force acting on it, which is called upthrust. In simple terms, the principle states that the buoyant force (F b) on an object is equal to the weight of the fluid displaced by the object, or the density of the fluid multiplied by the submerged volume (V) times the gravity (g) [1] [3]
The increase in weight is equal to the amount of liquid displaced by the object, which is the same as the volume of the suspended object times the density of the liquid. [1] The concept of Archimedes' principle is that an object immersed in a fluid is buoyed up by a force equal to the weight of the fluid displaced by the object. [2]
However, since water is in vast excess, the concentration of water is usually assumed to be constant and is omitted from equilibrium constant expressions. Often, the metal and the ligand are in competition for protons. [note 4] For the equilibrium p M + q L + r H ⇌ M p L q H r. a stability constant can be defined as follows: [28] [29]
The value of the equilibrium constant for the formation of a 1:1 complex, such as a host-guest species, may be calculated with a dedicated spreadsheet application, Bindfit: [4] In this case step 2 can be performed with a non-iterative procedure and the pre-programmed routine Solver can be used for step 3.
For a reversible reaction, the equilibrium constant can be measured at a variety of temperatures. This data can be plotted on a graph with ln K eq on the y-axis and 1 / T on the x axis. The data should have a linear relationship, the equation for which can be found by fitting the data using the linear form of the Van 't Hoff equation
In physical chemistry, Henry's law is a gas law that states that the amount of dissolved gas in a liquid is directly proportional at equilibrium to its partial pressure above the liquid. The proportionality factor is called Henry's law constant. It was formulated by the English chemist William Henry, who studied the topic in the early 19th ...
Suppose that a weight of mass m has been placed on top of the cylinder. It presses down on the top of the cylinder with a force of mg where g is the acceleration due to gravity. Suppose that x is smaller than its equilibrium value. The upward force of the gas is greater than the downward force of the weight, and if allowed to freely move, the ...