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The principle of corresponding states (CS principle or CSP) was first formulated by van der Waals, and it says that two fluids (subscript a and z) of a group (e.g. fluids of non-polar molecules) have approximately the same reduced molar volume (or reduced compressibility factor) when compared at the same reduced temperature and reduced pressure ...
Dimensionless numbers (or characteristic numbers) have an important role in analyzing the behavior of fluids and their flow as well as in other transport phenomena. [1] They include the Reynolds and the Mach numbers, which describe as ratios the relative magnitude of fluid and physical system characteristics, such as density, viscosity, speed of sound, and flow speed.
μ is the dynamic viscosity of the fluid (Pa·s = N·s/m 2 = kg/m·s) ρ is the density of the fluid (kg/m 3) Pe is the Peclet Number; Re is the Reynolds Number. The heat transfer analog of the Schmidt number is the Prandtl number (Pr). The ratio of thermal diffusivity to mass diffusivity is the Lewis number (Le).
One of the key predictions of the theory is the following relationship between viscosity , thermal conductivity, and specific heat : k = f μ c v {\displaystyle k=f\mu c_{v}} where f {\displaystyle f} is a constant which in general depends on the details of intermolecular interactions, but for spherically symmetric molecules is very close to 2. ...
The Archimedes number is applied often in the engineering of packed beds, which are very common in the chemical processing industry. [3] A packed bed reactor, which is similar to the ideal plug flow reactor model, involves packing a tubular reactor with a solid catalyst, then passing incompressible or compressible fluids through the solid bed. [3]
is the bulk fluid density; is the boundary layer density = (), the temperature difference between boundary layer and bulk fluid. There are two different ways to find the Grashof number from this point.
Viscosity is a measure of a fluid's rate-dependent resistance to a change in shape or to movement of its neighboring portions relative to one another. [1] For liquids, it corresponds to the informal concept of thickness; for example, syrup has a higher viscosity than water. [2]
Physically, volume viscosity represents the irreversible resistance, over and above the reversible resistance caused by isentropic bulk modulus, to a compression or expansion of a fluid. [1] At the molecular level, it stems from the finite time required for energy injected in the system to be distributed among the rotational and vibrational ...