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Mass transfer coefficients can be estimated from many different theoretical equations, correlations, and analogies that are functions of material properties, intensive properties and flow regime (laminar or turbulent flow). Selection of the most applicable model is dependent on the materials and the system, or environment, being studied.
In convective heat transfer, the Churchill–Bernstein equation is used to estimate the surface averaged Nusselt number for a cylinder in cross flow at various velocities. [1] The need for the equation arises from the inability to solve the Navier–Stokes equations in the turbulent flow regime, even for a Newtonian fluid .
Here, is the overall mass transfer coefficient, which could be determined by empirical correlations, is the surface area for mass transfer (particularly relevant in membrane-based separations), and ˙ is the mass flowrate of bulk fluid (e.g., mass flowrate of air in an application where water vapor is being separated from the air mixture). At ...
For best accuracy, n should be adjusted where correlations have a different exponent. We can take this further by substituting into this equation the definitions of the heat transfer coefficient, mass transfer coefficient, and Lewis number, yielding: = =
This rate can be quantified through the calculation and application of mass transfer coefficients for an overall process. These mass transfer coefficients are typically published in terms of dimensionless numbers, often including Péclet numbers, Reynolds numbers, Sherwood numbers, and Schmidt numbers, among others. [2] [3] [4]
This equation permits the prediction of an unknown transfer coefficient when one of the other coefficients is known. The analogy is valid for fully developed turbulent flow in conduits with Re > 10000, 0.7 < Pr < 160, and tubes where L/d > 60 (the same constraints as the Sieder–Tate correlation). The wider range of data can be correlated by ...
mass transfer (advection–diffusion problems; total momentum transfer to diffusive mass transfer) Prandtl number: Pr = = heat transfer (ratio of viscous diffusion rate over thermal diffusion rate) Pressure coefficient: C P
The heat transfer coefficient has SI units in watts per square meter per kelvin (W/(m 2 K)). The overall heat transfer rate for combined modes is usually expressed in terms of an overall conductance or heat transfer coefficient, U. In that case, the heat transfer rate is: ˙ = where (in SI units):
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