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Instead, both effects can also occur when the propagation direction of the electromagnetic wave together with the structure of an (achiral) material form a chiral experimental arrangement. [10] [11] This case, where the mutual arrangement of achiral components forms a chiral (experimental) arrangement, is known as extrinsic chirality. [12] [13]
Indirect enantiomer separation involves the interaction between the chiral analyte (CA) of interest and the suitable reactive CS (in this case it is an enantiopure chiral derivatizing agent, CDA) leading to the formation of a covalent diastereomeric complex that can be separated with an achiral chromatographic technique.
The achiral groups contain also transformations of determinant −1. In an achiral group, the orientation-preserving transformations form a (chiral) subgroup of index 2. Finite Coxeter groups or reflection groups are those point groups that are generated purely by a set of reflectional mirrors passing through the same point.
Chirality with hands and two enantiomers of a generic amino acid The direction of current flow and induced magnetic flux follow a "handness" relationship. The term chiral / ˈ k aɪ r əl / describes an object, especially a molecule, which has or produces a non-superposable mirror image of itself.
An object that is not chiral is said to be achiral. A chiral object and its mirror image are said to be enantiomorphs. The word chirality is derived from the Greek χείρ (cheir), the hand, the most familiar chiral object; the word enantiomorph stems from the Greek ἐναντίος (enantios) 'opposite' + μορφή (morphe) 'form'.
Practice theory (or praxeology, theory of social practices) is a body of social theory within anthropology and sociology that explains society and culture as the result of structure and individual agency. Practice theory emerged in the late 20th century and was first outlined in the work of the French sociologist Pierre Bourdieu.
A chiral phenomenon is one that is not identical to its mirror image (see the article on mathematical chirality).The spin of a particle may be used to define a handedness, or helicity, for that particle, which, in the case of a massless particle, is the same as chirality.
Homochirality is a uniformity of chirality, or handedness.Objects are chiral when they cannot be superposed on their mirror images. For example, the left and right hands of a human are approximately mirror images of each other but are not their own mirror images, so they are chiral.