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In thermodynamics, the bubble point is the temperature (at a given pressure) where the first bubble of vapor is formed when heating a liquid consisting of two or more components. [ 1 ] [ 2 ] Given that vapor will probably have a different composition than the liquid, the bubble point (along with the dew point ) at different compositions are ...
Figure 2: Change of pressure during bubble formation plotted as a function of added volume. Initially a bubble appears on the end of the capillary. As the size increases, the radius of curvature of the bubble decreases. At the point of the maximum bubble pressure, the bubble has a complete hemispherical shape whose radius is identical to the ...
Therefore the pressure step/stability method is the most recommended one for research and development applications. Additionally, the pressure step/stability measuring principle allows measuring the true First Bubble Point (FBP), in opposition to the pressure scan method, which only permits calculation the FBP at the selected flow rates.
The atmospheric pressure boiling point of a liquid (also known as the normal boiling point) is the temperature at which the vapor pressure equals the ambient atmospheric pressure. With any incremental increase in that temperature, the vapor pressure becomes sufficient to overcome atmospheric pressure and cause the liquid to form vapor bubbles.
The mole fraction of each component would correspond to where a point lies along a line starting at that component's corner and perpendicular to the opposite edge. The bubble point and dew point data would become curved surfaces inside a triangular prism, which connect the three boiling points on the vertical temperature "axes". Each face of ...
Therefore, multiple parameter sets for a single component are commonly used. A low-pressure parameter set is used to describe the vapour pressure curve up to the normal boiling point and the second set of parameters is used for the range from the normal boiling point to the critical point.
The above equations calculate the steady state mass flow rate for the pressure and temperature existing in the upstream pressure source. If the gas is being released from a closed high-pressure vessel, the above steady state equations may be used to approximate the initial mass flow rate. Subsequently, the mass flow rate decreases during the ...
The q-line (depicted in blue in Figure 1) intersects the point of intersection of the feed composition line and the x = y line and has a slope of q / (q - 1), where the parameter q denotes mole fraction of liquid in the feed. For example, if the feed is a saturated liquid, q = 1 and the slope of the q-line is infinite (drawn as a vertical line).