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Tantalum-Carbon Bond. Organotantalum chemistry is the chemistry of chemical compounds containing a carbon-to-tantalum chemical bond. A wide variety of compound have been reported, initially with cyclopentadienyl and CO ligands. Oxidation states vary from Ta(V) to Ta(-I).
The oxidation states are also maintained in articles of the elements (of course), and systematically in the table {{Infobox element/symbol-to-oxidation-state}} See also [ edit ]
Tantalum is a chemical element; it has symbol Ta and atomic number 73. It is named after Tantalus , a figure in Greek mythology. [ 11 ] Tantalum is a very hard, ductile , lustrous , blue-gray transition metal that is highly corrosion-resistant.
8, has been described as having a carbon oxidation state of − 8 / 3 . [19] Again, this is an average value since the structure of the molecule is H 3 C−CH 2 −CH 3, with the first and third carbon atoms each having an oxidation state of −3 and the central one −2.
When methane is oxidized to carbon dioxide its oxidation number changes from −4 to +4. Classical reductions include alkene reduction to alkanes and classical oxidations include oxidation of alcohols to aldehydes. In oxidations electrons are removed and the electron density of a molecule is reduced.
The distance from tantalum to the apical carbon atom is 2.11 Å, and to the basal carbon atoms is 2.180 Å. The distance from hydrogen to carbon in the methyl groups is 1.106 Å. The angle subtended by two basal carbon bonds is 82.2°, and the angle between the bonds to the apex and a carbon on the base is about 111.7°. [9] [10]
Tris(silox)tantalum, Ta(SiO t Bu 3) 3, is an organotantalum complex bound with three siloxide (this siloxide has three tert-butyl groups attached to silicon, attached via oxygen (t Bu 3 SiO-)) ligands. The tantalum center has a d-electron count of 2 and an oxidation state of III. The complex is trigonal planar whose point group is assigned as D 3h.
As quoted from this source in an online version of: J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 4; Table 4.1, Electronic Configuration and Properties of the Elements Touloukian, Y. S., Thermophysical Properties of Matter, Vol. 12, Thermal Expansion, Plenum, New York, 1975.