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Polycarboxylate Superplasticizer; Polycarboxylate superplasticizer (PCE), the third generation of high-performance superplasticizer, [9] follows the development of ordinary plasticizers and superplasticizers. It significantly reduces water content while enhancing concrete's workability, strength, and durability.
Structure of 1,2,3,4-butanetetracarboxylate, a low molecular weight polycarboxylate. Polycarboxylates are organic compounds with several carboxylic acid groups. Butane-1,2,3,4-tetracarboxylate is one example. Often, polycarboxylate refers to linear polymers with a high molecular mass (M r ≤ 100 000) and with many carboxylate groups.
Polycarboxylate ether superplasticizer (PCE) or just polycarboxylate (PC), work differently from sulfonate-based superplasticizers, giving cement dispersion by steric stabilisation. This form of dispersion is more powerful in its effect and gives improved workability retention to the cementitious mix.
These inexpensive products were derived from wood and paper industry, but are now advantageously replaced by other synthetic sulfonate and polycarboxylate, also known as superplasticizers. Water reducers offer several advantages in their use, listed below: reduces the water content by 5-10%; decreases the concrete porosity
Adsorbed or grafted polymers may form a protective layer around the particles, induce steric repulsive forces, and lead to steric stabilization at it is the case with polycarboxylate ether (PCE), the last generation of chemically tailored superplasticizer specifically designed to increase the workability of concrete while reducing its water ...
Naphthalenesulfonates are derivatives of sulfonic acid which contain a naphthalene functional unit. A related family of compounds are the aminonaphthalenesulfonic acids.Of commercial importance are the alkylnaphthalene sulfonates, which are used as superplasticizers in concrete.
Sodium polyacrylate (ACR, ASAP, or PAAS), [1]: 233 also known as waterlock, is a sodium salt of polyacrylic acid with the chemical formula [−CH 2 −CH(CO 2 Na)−] n and has broad applications in consumer products.
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