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Consider the first triangular diagram below, which shows all possible mixtures of methane, oxygen and nitrogen. Air is a mixture of about 21 volume percent oxygen, and 79 volume percent inerts (nitrogen). Any mixture of methane and air will therefore lie on the straight line between pure methane and pure air – this is shown as the blue air-line.
The stoichiometric mixture for a gasoline engine is the ideal ratio of air to fuel that burns all fuel with no excess air. For gasoline fuel, the stoichiometric air–fuel mixture is about 14.7:1 [1] i.e. for every one gram of fuel, 14.7 grams of air are required. For pure octane fuel, the oxidation reaction is:
The term is considered by many safety professionals to be the same as the lower explosive level (LEL). At a concentration in air lower than the LFL, gas mixtures are "too lean" to burn. Methane gas has an LFL of 4.4%. [1] If the atmosphere has less than 4.4% methane, an explosion cannot occur even if a source of ignition is present.
Methane is an important greenhouse gas, responsible for around 30% of the rise in global temperatures since the industrial revolution. [58] Methane has a global warming potential (GWP) of 29.8 ± 11 compared to CO 2 (potential of 1) over a 100-year period, and 82.5 ± 25.8 over a 20-year period. [59]
Many lighter-than-air balloons are made of aluminized plastic that limits such leakage; hydrogen and helium leak rapidly through latex balloons. However, methane is highly flammable and like hydrogen is not appropriate for use in passenger-carrying airships. It is also relatively dense and a potent greenhouse gas.
Methanol fuel is an alternative biofuel for internal combustion and other engines, either in combination with gasoline or independently. Methanol (CH 3 OH) is less expensive to sustainably produce than ethanol fuel, although it is more toxic than ethanol and has a lower energy density than gasoline.
For a gas that is a mixture of two or more pure gases (air or natural gas, for example), the gas composition must be known before compressibility can be calculated. Alternatively, the compressibility factor for specific gases can be read from generalized compressibility charts [ 1 ] that plot Z {\displaystyle Z} as a function of pressure at ...
Assuming initial atmospheric conditions (1 bar and 20 °C), the following table [1] lists the flame temperature for various fuels under constant pressure conditions. The temperatures mentioned here are for a stoichiometric fuel-oxidizer mixture (i.e. equivalence ratio φ = 1).