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Mole fraction is numerically identical to the number fraction, which is defined as the number of particles (molecules) of a constituent Ni divided by the total number of all molecules Ntot. Whereas mole fraction is a ratio of amounts to amounts (in units of moles per moles), molar concentration is a quotient of amount to volume (in units of ...
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
Volume fraction. In chemistry and fluid mechanics, the volume fraction is defined as the volume of a constituent Vi divided by the volume of all constituents of the mixture V prior to mixing: [1] Being dimensionless, its unit is 1; it is expressed as a number, e.g., 0.18. It is the same concept as volume percent (vol%) except that the latter is ...
Redlich–Kwong equation of state. In physics and thermodynamics, the Redlich–Kwong equation of state is an empirical, algebraic equation that relates temperature, pressure, and volume of gases. It is generally more accurate than the van der Waals equation and the ideal gas equation at temperatures above the critical temperature.
The two mole fractions often differ. These vapor and liquid mole fractions are represented by two points on the same horizontal isotherm (constant T ) line. When an entire range of temperatures vs. vapor and liquid mole fractions is graphed, two (usually curved) lines result. The lower one, representing the mole fraction of the boiling liquid ...
In simple words, we can say that the partial pressure of a gas in vapour phase is directly proportional to the mole fraction of a gas in solution. An example where Henry's law is at play is the depth-dependent dissolution of oxygen and nitrogen in the blood of underwater divers that changes during decompression , going to decompression sickness .
Mass fraction (chemistry) In chemistry, the mass fraction of a substance within a mixture is the ratio (alternatively denoted ) of the mass of that substance to the total mass of the mixture. [1] Expressed as a formula, the mass fraction is: Because the individual masses of the ingredients of a mixture sum to , their mass fractions sum to unity:
Lever rule. In chemistry, the lever rule is a formula used to determine the mole fraction (xi) or the mass fraction (wi) of each phase of a binary equilibrium phase diagram. It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.