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The dependence on m correlates with the oxidation state of the central atom, X: the higher the oxidation state the stronger the oxyacid. For example, p K a for HClO is 7.2, for HClO 2 is 2.0, for HClO 3 is −1 and HClO 4 is a strong acid ( p K a ≪ 0 ). [ 7 ]
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the Van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
In chemistry, biochemistry, and pharmacology, a dissociation constant (K D) is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, as when a complex falls apart into its component molecules, or when a salt splits up into its component ions.
Chloroform, [10] or trichloromethane (often abbreviated as TCM), is an organochloride with the formula C H Cl 3 and a common solvent. It is a volatile , colorless, sweet-smelling, dense liquid produced on a large scale as a precursor to refrigerants and PTFE . [ 11 ]
For strongly temperature-dependent α, this approximation is only useful for small temperature differences ΔT. Temperature coefficients are specified for various applications, including electric and magnetic properties of materials as well as reactivity. The temperature coefficient of most of the reactions lies between 2 and 3.
The concentration of the species LH is equal to the sum of the concentrations of the two micro-species with the same chemical formula, labelled L 1 H and L 2 H. The constant K 2 is for a reaction with these two micro-species as products, so that [LH] = [L 1 H] + [L 2 H] appears in the numerator, and it follows that this macro-constant is equal ...
All thermodynamic data is a non-linear function of temperature (and pressure), but there is no universal equation format for expressing the various functions. Here we describe a commonly used polynomial equation to express the temperature dependence of the heat content. A common six-term equation for the isobaric heat content is:
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".