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Anhydrous aluminium chloride is hygroscopic, having a very pronounced affinity for water. It fumes in moist air and hisses when mixed with liquid water as the Cl − ligands are displaced with H 2 O molecules to form the hexahydrate [Al(H 2 O) 6]Cl 3. The anhydrous phase cannot be regained on heating the hexahydrate.
The temperature of the solution eventually decreases to match that of the surroundings. The equilibrium, between the gas as a separate phase and the gas in solution, will by Le Châtelier's principle shift to favour the gas going into solution as the temperature is decreased (decreasing the temperature increases the solubility of a gas).
The equilibrium fraction of decomposed molecules increases with the temperature. Since thermal decomposition is a kinetic process, the observed temperature of its beginning in most instances will be a function of the experimental conditions and sensitivity of the experimental setup.
The strength of the bonds between the metal ion and water molecules in the primary solvation shell increases with the electrical charge, z, on the metal ion and decreases as its ionic radius, r, increases. Aqua ions are subject to hydrolysis. The logarithm of the first hydrolysis constant is proportional to z 2 /r for most aqua ions.
In some contexts, water of crystallization is the total mass of water in a substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the crystalline framework of a metal complex or a salt, which is not directly bonded to the metal cation.
At the very high temperature of 3,000 °C (3,270 K; 5,430 °F) more than half of the water molecules are decomposed. At ambient temperatures only one molecule in 100 trillion dissociates by the effect of heat. [15] The high temperature requirements and material constraints have limited the applications of the thermal decomposition approach.
[1] [2] As water is an excellent solvent and is also naturally abundant, it is a ubiquitous solvent in chemistry. Since water is frequently used as the solvent in experiments, the word solution refers to an aqueous solution, unless the solvent is specified. [3] [4] A non-aqueous solution is a solution in which the solvent is a liquid, but is ...
Melting temperature as a function of HCl concentration in water [29] [30] Physical properties of hydrochloric acid, such as boiling and melting points, density, and pH, depend on the concentration or molarity of HCl in the aqueous solution. They range from those of water at very low concentrations approaching 0% HCl to values for fuming ...