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Phosphorus pentoxide crystallizes in at least four forms or polymorphs.The most familiar one, a metastable form [1] (shown in the figure), comprises molecules of P 4 O 10.Weak van der Waals forces hold these molecules together in a hexagonal lattice (However, in spite of the high symmetry of the molecules, the crystal packing is not a close packing [2]).
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
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The values in an NPK fertilizer label are related to the concentrations (by weight) of phosphorus and potassium elements as follows: P 2 O 5 consists of 56.4% elemental oxygen and 43.6% elemental phosphorus by weight.
A general formula for such cyclic compounds is [HPO 3] x where x = number of phosphoric units in the molecule. When metaphosphoric acids lose their hydrogens as H +, cyclic anions called metaphosphates are formed. An example of a compound with such an anion is sodium hexametaphosphate (Na 6 P 6 O 18), used as a sequestrant and a food additive.
These compounds are between ionic and covalent compounds and thus have unusual bonding properties. [4] These elements are also noted for their stability in compounds due to their tendency to form covalent double bonds and triple bonds. This property of these elements leads to their potential toxicity, most evident in phosphorus, arsenic, and ...
These compounds react with water to form phosphine. Other phosphides , for example Na 3 P 7 , are known for these reactive metals. With the transition metals as well as the monophosphides there are metal-rich phosphides, which are generally hard refractory compounds with a metallic lustre, and phosphorus-rich phosphides which are less stable ...
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