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Reduction 4H + + 4e − → 2H 2 E° = 0.00 V vs. NHE Overall 2H 2 O → 2H 2 + O 2 E°cell = +1.23 V; ΔG = 475 kJ/mol . Water splitting can be done at higher pH values as well however the standard potentials will vary according to the Nernst equation and therefore shift by -59 mV for each pH unit increase. However, the total cell potential ...
In the case of water electrolysis, Gibbs free energy represents the minimum work necessary for the reaction to proceed, and the reaction enthalpy is the amount of energy (both work and heat) that has to be provided so the reaction products are at the same temperature as the reactant (i.e. standard temperature for the values given above ...
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
Water splitting is the chemical reaction in which water is broken down into oxygen and hydrogen: [1] 2 H 2 O → 2 H 2 + O 2 Efficient and economical water splitting would be a technological breakthrough that could underpin a hydrogen economy .
In chemistry, the rate equation (also known as the rate law or empirical differential rate equation) is an empirical differential mathematical expression for the reaction rate of a given reaction in terms of concentrations of chemical species and constant parameters (normally rate coefficients and partial orders of reaction) only. [1]
In the breakdown of a compound into its constituent parts, the generalized reaction for chemical decomposition is: AB → A + B (AB represents the reactant that begins the reaction, and A and B represent the products of the reaction) An example is the electrolysis of water to the gases hydrogen and oxygen: 2 H 2 O(l) → 2 H 2 (g) + O 2 (g)
where k f and k b are the reaction rate constants, with units of frequency (1/time) and c o and c r are the surface concentrations (mol/area) of the oxidized and reduced molecules, respectively (written as c o (0,t) and c r (0,t) in the previous section). The net rate of reaction v and net current density j are then: [Note 2]
Hydrolysis (/ h aɪ ˈ d r ɒ l ɪ s ɪ s /; from Ancient Greek hydro- 'water' and lysis 'to unbind') is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile. [1]