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Solutions containing magnesium sulfate are generally more aggressive, for the same concentration. This is because magnesium also takes part in the reactions, replacing calcium in the solid phases with the formation of brucite (magnesium hydroxide) and magnesium silicate hydrates. The displaced calcium precipitates mainly as gypsum.
Magnesium sulfate is used to prepare specific cements by the reaction between magnesium oxide and magnesium sulfate solution, which are of good binding ability and more resistance than Portland cement. This cement is mainly utilized in the production of lightweight insulation panels, although its poor water resistance limits its usage.
Sorel cement (also known as magnesia cement or magnesium oxychloride) is a non-hydraulic cement first produced by the French chemist Stanislas Sorel in 1867. [1]In fact, in 1855, before working with magnesium compounds, Stanislas Sorel first developed a two-component cement by mixing zinc oxide powder with a solution of zinc chloride.
These mineral layers somewhat protect the concrete from other processes, which includes attack by magnesium, chloride and sulfate ions and carbonatation. Above the water surface, mechanical damage may occur by erosion by waves themselves or sand and gravel they carry, and by crystallization of salts from water soaking into the concrete pores ...
Selenitic lime, also known as Scotts' cement after Henry Young Darracott Scott, is a cement of grey chalk or similar lime, such as in the Lias Group, with about 5% added gypsum plaster (calcined gypsum). [13] Selenite is a type of gypsum, but selenitic cement may be made using any form of sulfate or sulfuric acid. [18]
GGBS cement is routinely specified in concrete to provide protection against both sulfate attack and chloride attack. GGBS has now effectively replaced sulfate-resisting Portland cement (SRPC) on the market for sulfate resistance because of its superior performance and greatly reduced cost compared to SRPC.
Concrete is a mixture of coarse (stone or brick chips) and fine (generally sand and/or crushed stone) aggregates with a paste of binder material (usually Portland cement) and water. When cement is mixed with a small amount of water, it hydrates to form microscopic opaque crystal lattices encapsulating and locking the aggregate into a rigid shape.
Lignosulfonates are also used during the production of cement, where they act as grinding aids in the cement mill and as a rawmix slurry deflocculant (that reduces the viscosity of the slurry). Lignosulfonates are also used for the production of plasterboard to reduce the amount of water required to make the stucco flow and form the layer ...
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