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Hydrogen fluoride (fluorane) is an inorganic compound with chemical formula H F. It is a very poisonous, colorless gas or liquid that dissolves in water to yield hydrofluoric acid .
Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water.Solutions of HF are colorless, acidic and highly corrosive.A common concentration is 49% (48-52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling point near room temperature.
Hydrogen bonding amongst HF molecules gives rise to high viscosity in the liquid phase and lower than expected pressure in the gas phase. Hydrogen fluoride does not boil until 20 °C in contrast to the heavier hydrogen halides which boil between −85 °C and −35 °C (−120 °F and –30 °F).
Hydrogen and fluorine combine to yield hydrogen fluoride, in which discrete molecules form clusters by hydrogen bonding, resembling water more than hydrogen chloride. [126] [127] [128] It boils at a much higher temperature than heavier hydrogen halides and unlike them is miscible with water. [129] Hydrogen fluoride readily hydrates on contact ...
The hydrogen halides are diatomic molecules with no tendency to ionize in the gas phase (although liquified hydrogen fluoride is a polar solvent somewhat similar to water). Thus, chemists distinguish hydrogen chloride from hydrochloric acid. The former is a gas at room temperature that reacts with water to give the acid.
This neutralization reaction forms hydrogen fluoride (HF), the conjugate acid of fluoride. In aqueous solution, fluoride has a pK b value of 10.8. It is therefore a weak base, and tends to remain as the fluoride ion rather than generating a substantial amount of hydrogen fluoride. That is, the following equilibrium favours the left-hand side in ...
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Humphry Davy, as well as the notable French chemists Joseph Louis Gay-Lussac and Louis Jacques Thénard, experienced severe pains from inhaling hydrogen fluoride gas; Davy's eyes were damaged. Irish chemists Thomas and George Knox developed fluorite apparatus for working with hydrogen fluoride, but nonetheless were severely poisoned. Thomas ...