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As a side effect of the process, some carbon nuclei fuse with additional helium to produce a stable isotope of oxygen and energy: 12 6 C + 4 2 He → 16 8 O + γ (+7.162 MeV) Nuclear fusion reactions of helium with hydrogen produces lithium-5, which also is highly unstable, and decays back into smaller nuclei with a half-life of 3.7 × 10 −22 s.
As a result, there is little mixing of fresh hydrogen into the core or fusion products outward. In higher-mass stars, the dominant energy production process is the CNO cycle, which is a catalytic cycle that uses nuclei of carbon, nitrogen and oxygen as intermediaries and in the end produces a helium nucleus as with the proton–proton chain. [22]
The other class is a cycle of reactions called the triple-alpha process, which consumes only helium, and produces carbon. [1] The alpha process most commonly occurs in massive stars and during supernovae. Both processes are preceded by hydrogen fusion, which produces the helium that fuels both the triple-alpha process and the alpha ladder ...
The subsequent nucleosynthesis of heavier elements (Z ≥ 6, carbon and heavier elements) requires the extreme temperatures and pressures found within stars and supernovae. These processes began as hydrogen and helium from the Big Bang collapsed into the first stars after about 500 million years.
Helium is the smallest and the lightest noble gas and one of the most unreactive elements, so it was commonly considered that helium compounds cannot exist at all, or at least under normal conditions. [1] Helium's first ionization energy of 24.57 eV is the highest of any element. [2]
Once temperatures are lowered, out of every 16 nucleons (2 neutrons and 14 protons), 4 of these (25% of the total particles and total mass) combine quickly into one helium-4 nucleus. This produces one helium for every 12 hydrogens, resulting in a universe that is a little over 8% helium by number of atoms, and 25% helium by mass.
The length of the carbonhydrogen bond varies slightly with the hybridisation of the carbon atom. A bond between a hydrogen atom and an sp 2 hybridised carbon atom is about 0.6% shorter than between hydrogen and sp 3 hybridised carbon. A bond between hydrogen and sp hybridised carbon is shorter still, about 3% shorter than sp 3 C-H.
The deuterium bottleneck in the formation of helium, together with the lack of stable ways for helium to combine with hydrogen or with itself (no stable nucleus has a mass number of 5 or 8) meant that an insignificant amount of carbon, or any elements heavier than carbon, formed in the Big Bang. These elements thus required formation in stars.