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Acids and bases. A Lewis acid (named for the American physical chemist Gilbert N. Lewis) is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct. A Lewis base, then, is any species that has a filled orbital containing an electron pair which is not involved in ...
A good example is the formation of adducts between the Lewis acid borane and the oxygen atom in the Lewis bases, tetrahydrofuran (THF): BH 3 ·O(CH 2) 4 or diethyl ether: BH 3 ·O(CH 3 CH 2) 2. Many Lewis acids and Lewis bases reacting in the gas phase or in non-aqueous solvents to form adducts have been examined in the ECW model. [3]
Coordinate covalent bond. In coordination chemistry, a coordinate covalent bond, [1] also known as a dative bond, [2] dipolar bond, [1] or coordinate bond[3] is a kind of two-center, two-electron covalent bond in which the two electrons derive from the same atom. The bonding of metal ions to ligands involves this kind of interaction. [4]
[15] In Lewis theory an acid, A, and a base, B, form an adduct, AB, where the electron pair forms a dative covalent bond between A and B. This is shown when the adduct H 3 N−BF 3 forms from ammonia and boron trifluoride, a reaction that cannot occur in water because boron trifluoride hydrolizes in water. [16]
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In organic chemistry, an addition reaction is an organic reaction in which two or more molecules combine to form a larger molecule called the adduct. [1][2] An addition reaction is limited to chemical compounds that have multiple bonds. Examples include a molecule with a carbon–carbon double bond (an alkene) or a triple bond (an alkyne).
Borane, also known as borine, is an unstable and highly reactive molecule with the chemical formula B H. 3. The preparation of borane carbonyl, BH 3 (CO), played an important role in exploring the chemistry of boranes, as it indicated the likely existence of the borane molecule. [2] However, the molecular species BH 3 is a very strong Lewis acid.
Aluminylene. The general structure of an aluminylene compound. Aluminylenes are a sub-class of aluminium (I) compounds that feature singly-coordinated aluminium atoms with a lone pair of electrons . As aluminylenes exhibit two unoccupied orbitals, they are not strictly aluminium analogues of carbenes until stabilized by a Lewis base to form ...