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In chemistry, molecular symmetry describes the symmetry present in molecules and the classification of these molecules according to their symmetry. Molecular symmetry is a fundamental concept in chemistry, as it can be used to predict or explain many of a molecule's chemical properties , such as whether or not it has a dipole moment , as well ...
This lists the character tables for the more common molecular point groups used in the study of molecular symmetry. These tables are based on the group-theoretical treatment of the symmetry operations present in common molecules, and are useful in molecular spectroscopy and quantum chemistry. Information regarding the use of the tables, as well ...
In crystallography, a crystallographic point group is a three dimensional point group whose symmetry operations are compatible with a three dimensional crystallographic lattice. According to the crystallographic restriction it may only contain one-, two-, three-, four- and sixfold rotations or rotoinversions. This reduces the number of ...
The direction of a symmetry element corresponds to its position in the Hermann–Mauguin symbol. If a rotation axis n and a mirror plane m have the same direction, then they are denoted as a fraction n / m or n /m. If two or more axes have the same direction, the axis with higher symmetry is shown.
D nh is the symmetry group for a "regular" n-gonal prism and also for a "regular" n-gonal bipyramid. D nd is the symmetry group for a "regular" n-gonal antiprism, and also for a "regular" n-gonal trapezohedron. D n is the symmetry group of a partially rotated ("twisted") prism. The groups D 2 and D 2h are noteworthy in that there is no special ...
The irreducible complex characters of a finite group form a character table which encodes much useful information about the group G in a concise form. Each row is labelled by an irreducible character and the entries in the row are the values of that character on any representative of the respective conjugacy class of G (because characters are class functions).
The Bauhinia blakeana flower on the Hong Kong region flag has C 5 symmetry; the star on each petal has D 5 symmetry. The Yin and Yang symbol has C 2 symmetry of geometry with inverted colors In geometry , a point group is a mathematical group of symmetry operations ( isometries in a Euclidean space ) that have a fixed point in common.
The Laporte rule is powerful because it applies to complexes that deviate from idealized O h symmetry. For example, the d-d transitions for [Cr(NH 3) 5 Cl] 2+ are weak (ε < 100) even though the complex is only of C 4v symmetry. [5] The Laporte rule helps explain the intense colors often observed for the tetrahedral complexes.