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Copper(II) thiocyanate can be prepared from the reaction of concentrated solutions of copper(II) and a soluble thiocyanate salt in water, precipitating as a black powder. [2] [3] With rapid drying, pure Cu(SCN) 2 can be isolated. Reaction at lower concentrations and for longer periods of time generates instead copper(I) thiocyanate. [4]
All data as presented in these tables is for materials in their standard state, which is at 25 °C and 100 kPa by definition. If values are given for other conditions, this is explicitly indicated. If values are given for other conditions, this is explicitly indicated.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
Thiocyanate [6] is known to be an important part in the biosynthesis of hypothiocyanite by a lactoperoxidase. [7] [8] [9] Thus the complete absence of thiocyanate or reduced thiocyanate [10] in the human body, (e.g., cystic fibrosis) is damaging to the human host defense system.
In methyl thiocyanate, N≡C and C−S distances are 116 and 176 pm. By contrast, N=C and C=S distances are 117 and 158 pm in isothiocyanates. [7] Typical bond angles for C−S−C are 100°. [3] By contrast C−N=C in aryl isothiocyanates is 165°. Again, the thiocyanate isomers are quite different with C−S−C angle near 100°.
Copper is a chemical element with the symbol Cu (from Latin: cuprum) and the atomic number of 29. It is easily recognisable, due to its distinct red-orange color.Copper also has a range of different organic and inorganic salts, having varying oxidation states ranging from (0,I) to (III).
Copper(I) thiocyanate is a hole conductor, a semiconductor with a wide band gap (3.6 eV, therefore transparent to visible and near infrared light). [11] It is used in photovoltaics in some third-generation cells as a hole transfer layer.