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Tin(IV) nitrate reacts with trifloroacetic acid anhydride to yield (NO 2 +) 2 [Sn(OOCCF 3) 6 2−] which is a nitronium salt. With trifluoroacetic acid a similar compound solvated with trifluoroacetic acid is produced. [6] It also reacts with acetic anhydride or acetic acid to produce tin(IV) acetate and with nitric oxide to produce tin(IV ...
Titanium nitride (TiN; sometimes known as tinite) is an extremely hard ceramic material, often used as a physical vapor deposition (PVD) coating on titanium alloys, steel, carbide, and aluminium components to improve the substrate's surface properties.
Tin(II) chloride, also known as stannous chloride, is a white crystalline solid with the formula Sn Cl 2. It forms a stable dihydrate, but aqueous solutions tend to undergo hydrolysis, particularly if hot. SnCl 2 is widely used as a reducing agent (in acid solution), and in electrolytic baths for tin-plating.
In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
Tin is a post-transition metal in group 14 of the periodic table of elements. It is obtained chiefly from the mineral cassiterite, which contains stannic oxide, SnO 2. Tin shows a chemical similarity to both of its neighbors in group 14, germanium and lead, and has two main oxidation states, +2 and the slightly more stable
With sulfur dioxide, the products are NO and N 2 O; with tin(II) (Sn 2+) the product is hyponitrous acid (H 2 N 2 O 2); reduction all the way to ammonia (NH 3) occurs with hydrogen sulfide. With the hydrazinium cation (N 2 H + 5) the product of nitrite reduction is hydrazoic acid (HN 3), an unstable and explosive compound: HNO 2 + N 2 H + 5 → ...
Titanium nitrate is the inorganic compound with formula Ti(NO 3) 4. It is a colorless, diamagnetic solid that sublimes readily. It is an unusual example of a volatile binary transition metal nitrate. Ill defined species called titanium nitrate are produced upon dissolution of titanium or its oxides in nitric acid.
The fundamental reasons why TiAlN coatings outperform pure Titanium nitride (TiN) coatings are considered to be: Increased oxidation resistance at elevated temperatures due to the formation of a protective aluminium-oxide layer at the surface; Increased hardness in the freshly deposited films due to micro-structure changes and solid solution ...