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The general formula of a phosphoric acid is H n−2x+2 P n O 3n−x+1, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure; that is, the minimum number of bonds that would have to be broken to eliminate all cycles.
Contrary to biology, biochemistry and biomedicine branches, in organic and inorganic chemistry branches, and in the branch of chemical nomenclature (see IUPAC), the correct name for the −P(=O)(−O −) 2 group is not "phosphoryl", but phosphonato, and the correct name for the −P(=O)(−OH) 2 group is phosphono, and the term phosphoryl ...
Phosphorus has an oxidation number of −3 in phosphine. Phosphine is produced by hydrolysis of calcium phosphide, Ca 3 P 2. Unlike ammonia, phosphine is oxidised by air. Phosphine is also far less basic than ammonia. Other phosphines are known which contain chains of up to nine phosphorus atoms and have the formula P n H n+2. [31]
Phosphorus comprises 0.1% by mass of the average rock [12] (while, for perspective, its typical concentration in vegetation is 0.03% to 0.2%), [13] and consequently there are quadrillions of tons of phosphorus in Earth's 3×10 19-ton crust, [14] albeit at predominantly lower concentration than the deposits counted as reserves, which are ...
Their generic formula is H n−x+2 P n O 3n−x+1, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure. These acids, and their esters and salts ("phosphates") include some of the best-known and most important compounds of phosphorus. Orthophosphoric acid, H 3 PO 4. The simplest member ...
The phosphorus atom in phosphines has a formal oxidation state −3 (σ 3 λ 3) and are the phosphorus analogues of amines. Like amines, phosphines have a trigonal pyramidal molecular geometry although often with smaller C-E-C angles (E = N, P), at least in the absence of steric effects.
Phosphorous acid (or phosphonic acid) is the compound described by the formula H 3 PO 3. This acid is diprotic (readily ionizes two protons), not triprotic as might be suggested by this formula. Phosphorous acid is an intermediate in the preparation of other phosphorus compounds.
A phosphorane (IUPAC name: λ 5-phosphane) is a functional group in organophosphorus chemistry with pentavalent phosphorus. Phosphoranes have the general formula PR 5. Phosphoranes of the type PX 5 adopt a trigonal bipyramidal molecular geometry with the two apical bonds longer than the three equatorial bonds.