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Methylene diphenyl diisocyanate (MDI) is an aromatic diisocyanate. Three isomers are common, varying by the positions of the isocyanate groups around the rings: 2,2′-MDI, 2,4′-MDI, and 4,4′-MDI. The 4,4′ isomer is most widely used, and is also known as 4,4′-diphenylmethane diisocyanate. [3] This isomer is also known as Pure MDI.
The global market for diisocyanates in the year 2000 was 4.4 million tonnes, of which 61.3% was methylene diphenyl diisocyanate (MDI), 34.1% was toluene diisocyanate (TDI), 3.4% was the total for hexamethylene diisocyanate (HDI) and isophorone diisocyanate (IPDI), and 1.2% was the total for various others. [18]
More specifically, it is an aliphatic diisocyanate. It is a water white liquid at room temperature and is manufactured in relatively small quantities. It is also known as 4,4'-methylenedi(cyclohexyl isocyanate) or methylene bis(4-cyclohexylisocyanate) [2] and has the formula CH 2 [(C 6 H 10)NCO] 2.
4,4′-Methylenedianiline (MDA) is an organic compound with the formula CH 2 (C 6 H 4 NH 2) 2. It is a colorless solid, although commercial samples can appear yellow or brown. It is a colorless solid, although commercial samples can appear yellow or brown.
Skeletal formula of 4,4'-methylene diphenyl diisocyanate (4,4'-MDI, Pure MDI). Created using ACD/ChemSketch 10.0 and Inkscape. Date: 5 October 2007: Source: Own work: Author: Fvasconcellos 16:37, 6 October 2007 (UTC) Permission (Reusing this file)
A diisocyanate, often 4,4’-methylenediphenyldiisocyanate (MDI), is reacted with trimellitic anhydride (TMA). The product achieved at the end of this process is a high molecular weight, fully imidized polymer solution with no condensation byproducts, since the carbon dioxide gas byproduct is easily removed.
Phenyl isocyanate is an organic compound typically abbreviated PhNCO. The molecule consists of a phenyl ring attached to the isocyanate functional group.It is a colourless liquid that reacts with water.
Polymethylene polyphenylene isocyanate (PPI), is a polyurea-based polymer derived from isocyanate monomers that is used in some glues, aerosol foams, plastics, paint and household products.