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Aluminium nitrate cannot be synthesized by the reaction of aluminium with concentrated nitric acid, as the aluminium forms a passivation layer. Aluminium nitrate may instead be prepared by the reaction of nitric acid with aluminium(III) chloride. Nitrosyl chloride is produced as a by-product; it bubbles out of the solution as a gas.
aluminium chloride fluoride: 22395-91-1 AlClO: aluminium chloride oxide: 13596-11-7 AlCl 2 H: dichloroalumane: 16603-84-2 AlCl 3: aluminium chloride: 16603-84-2 AlCl 2 F: aluminium chloride fluoride: 13497-96-6 AlCl 3: aluminium trichloride: 7446-70-0 AlCl 4 Cs: aluminium caesium tetrachloride: 17992-03-9 AlCl 4 K: potassium ...
Tetranitratoaluminate salts are not completely stable and can decompose to the nitrates and aluminium oxynitrates. [3] When nitronium tetranitratoaluminate is sublimed it can form anhydrous aluminium nitrate. [2] Nitronium tetranitratoaluminate dissolved in a nitric acid and dinitrogen pentoxide mixture yields the hexanitratoaluminate complex.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
For example, aluminium monoxide, AlO, has been detected in the gas phase after explosion [19] and in stellar absorption spectra. [20] More thoroughly investigated are compounds of the formula R 4 Al 2 which contain an Al–Al bond and where R is a large organic ligand. [21]
Aluminates are often formulated as a combination of basic oxide and aluminium oxide, for example the formula of anhydrous sodium aluminate NaAlO 2 would be shown as Na 2 O·Al 2 O 3. A number of aluminate oxyanions are known: The simplest is the approximately tetrahedral AlO 5− 4 found in the compound Na 5 AlO 4, [2] framework AlO −
Being the conjugate base of a strong acid (nitric acid, pK a = -1.4), nitrate has modest Lewis basicity.Two coordination modes are common: unidentate and bidentate.Often, bidentate nitrate, denoted κ 2-NO 3, is bound unsymmetrically in the sense that one M-O distance is clearly bonding and the other is more weakly interacting. [2]
Hexanitratoaluminate is an anion of aluminium and six nitrate groups with formula [Al(NO 3) 6] 3− that can form salts called hexanitratoaluminates. Related compounds [ edit ]