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A silicon–oxygen bond (Si−O bond) is a chemical bond between silicon and oxygen atoms that can be found in many inorganic and organic compounds. [1] In a silicon–oxygen bond, electrons are shared unequally between the two atoms, with oxygen taking the larger share due to its greater electronegativity.
The C–Si bond is somewhat polarised towards carbon due to carbon's greater electronegativity (C 2.55 vs Si 1.90), and single bonds from Si to electronegative elements are very strong. [14] Silicon is thus susceptible to nucleophilic attack by O − , Cl − , or F − ; the energy of an Si–O bond in particular is strikingly high.
Orthosilicic acid (/ ˌ ɔːr θ ə s ɪ ˈ l ɪ s ɪ k /) is an inorganic compound with the formula Si(O H) 4. Although rarely observed, it is the key compound of silica and silicates and the precursor to other silicic acids [H 2x SiO x+2] n. Silicic acids play important roles in biomineralization and technology.
In chemistry, a silicic acid (/ s ɪ ˈ l ɪ s ɪ k /) is any chemical compound containing the element silicon attached to oxide (=O) and hydroxyl (−OH) groups, with the general formula [H 2x SiO x+2] n or, equivalently, [SiO x (OH) 4−2x] n. [1] [2] Orthosilicic acid is a representative example.
Silicon compounds are compounds containing the element silicon (Si). As a carbon group element, silicon often forms compounds in the +4 oxidation state, though many unusual compounds have been discovered that differ from expectations based on its valence electrons, including the silicides and some silanes.
Alternative depiction of a metasilicate chain emphasizing the Si-O bonds. With two shared oxides bound to each silicon, cyclic or polymeric structures can result. The cyclic metasilicate ring Si 6 O 12− 18 is a hexamer of SiO 3 2-. Polymeric silicate anions of can exist also as long chains.
They feature Si-Si bonds. Attracting more interest are the organic derivatives such as polydimethylsilane ((CH 3) 2 Si) n. Dodecamethylcyclohexasilane ((CH 3) 2 Si) 6 is an oligomer of such materials. Formally speaking, polysilanes also include compounds of the type (SiH 2)n, but these less studied. Carbosilanes are polymeric silanes with ...
A silanol is a functional group in silicon chemistry with the connectivity Si–O–H. It is related to the hydroxy functional group (C–O–H) found in all alcohols. Silanols are often invoked as intermediates in organosilicon chemistry and silicate mineralogy. [1] If a silanol contains one or more organic residues, it is an organosilanol.