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In electrochemistry, the electrochemical potential of electrons (or any other species) is the total potential, including both the (internal, nonelectrical) chemical potential and the electric potential, and is by definition constant across a device in equilibrium, whereas the chemical potential of electrons is equal to the electrochemical ...
The phrase "chemical potential" sometimes means "total chemical potential", but that is not universal. [13] In some fields, in particular electrochemistry, semiconductor physics, and solid-state physics, the term "chemical potential" means internal chemical potential, while the term electrochemical potential is used to mean total chemical ...
The pseudopotential is an attempt to replace the complicated effects of the motion of the core (i.e. non-valence) electrons of an atom and its nucleus with an effective potential, or pseudopotential, so that the Schrödinger equation contains a modified effective potential term instead of the Coulombic potential term for core electrons normally found in the Schrödinger equation.
When a chemical reaction is driven by an electrical potential difference, as in electrolysis, or if a potential difference results from a chemical reaction as in an electric battery or fuel cell, it is called an electrochemical reaction. Unlike in other chemical reactions, in electrochemical reactions electrons are not transferred directly ...
An example is the muon, with a mean lifetime of 2.2 × 10 −6 seconds, which decays into an electron, a muon neutrino and an electron antineutrino. The electron, on the other hand, is thought to be stable on theoretical grounds: the electron is the least massive particle with non-zero electric charge, so its decay would violate charge ...
The chemical potential μ is, by definition, the energy of adding an extra electron to the fluid. This energy may be decomposed into a kinetic energy T part and the potential energy − eφ part. Since the chemical potential is kept constant, Δ μ = Δ T − e Δ ϕ = 0. {\displaystyle \Delta \mu =\Delta T-e\Delta \phi =0.}
At a real surface the potential is influenced by image charges and the formation of surface dipoles and it rather looks as indicated by the dashed line. Given the potential in Figure 1, it can be shown that the one-dimensional single-electron Schrödinger equation gives two qualitatively different types of solutions. [4]
There are various types of potential energy, each associated with a particular type of force. For example, the work of an elastic force is called elastic potential energy; work of the gravitational force is called gravitational potential energy; work of the Coulomb force is called electric potential energy; work of the strong nuclear force or weak nuclear force acting on the baryon charge is ...