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Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
The ideal gas law is the equation of state for an ideal gas, given by: = where P is the pressure; V is the volume; n is the amount of substance of the gas (in moles) T is the absolute temperature; R is the gas constant, which must be expressed in units consistent with those chosen for pressure, volume and temperature.
The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called gas laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
The gas constant occurs in the ideal gas law: = = where P is the absolute pressure, V is the volume of gas, n is the amount of substance, m is the mass, and T is the thermodynamic temperature. R specific is the mass-specific gas constant. The gas constant is expressed in the same unit as molar heat.
If the calorically perfect gas approximation is used, then the ideal gas law may also be expressed as follows = where is the number density of the gas (number of atoms/molecules per unit volume), = / is the (constant) adiabatic index (ratio of specific heats), = is the internal energy per unit mass (the "specific internal energy"), is the ...
Macroscopically, the ideal gas law states that, for an ideal gas, the product of pressure p and volume V is proportional to the product of amount of substance n and absolute temperature T: =, where R is the molar gas constant (8.314 462 618 153 24 J⋅K −1 ⋅mol −1). [4]
Ideal gas law; S. Sackur–Tetrode equation; Scale-free ideal gas This page was last edited on 10 August 2024, at 04:02 (UTC). Text is available under the ...
The classical equipartition theorem predicts that the heat capacity ratio (γ) for an ideal gas can be related to the thermally accessible degrees of freedom (f) of a molecule by = +, =. Thus we observe that for a monatomic gas, with 3 translational degrees of freedom per atom: γ = 5 3 = 1.6666 … , {\displaystyle \gamma ={\frac {5}{3}}=1. ...