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The ratio of two extensive properties of the same object or system is an intensive property. For example, the ratio of an object's mass and volume, which are two extensive properties, is density, which is an intensive property. [10] More generally properties can be combined to give new properties, which may be called derived or composite ...
The specific volume, an intensive property, is the system's volume per unit mass. Volume is a function of state and is interdependent with other thermodynamic properties such as pressure and temperature. For example, volume is related to the pressure and temperature of an ideal gas by the ideal gas law.
The number of degrees of freedom F (also called the variance) is the number of independent intensive properties, i.e., the largest number of thermodynamic parameters such as temperature or pressure that can be varied simultaneously and independently of each other. [5] An example of a one-component system (C = 1) is a pure chemical
Some constants, such as the ideal gas constant, R, do not describe the state of a system, and so are not properties. On the other hand, some constants, such as K f (the freezing point depression constant, or cryoscopic constant ), depend on the identity of a substance, and so may be considered to describe the state of a system, and therefore ...
Specific volume is an example of an intensive property because it is the ratio of volume occupied by a unit of mass of a gas that is identical throughout a system at equilibrium. [ 17 ] 1000 atoms a gas occupy the same space as any other 1000 atoms for any given temperature and pressure.
The three "standard" properties are in fact the three possible second derivatives of the Gibbs free energy with respect to temperature and pressure. Moreover, considering derivatives such as ∂ 3 G ∂ P ∂ T 2 {\displaystyle {\frac {\partial ^{3}G}{\partial P\partial T^{2}}}} and the related Schwartz relations, shows that the properties ...
The heat content of an ideal gas is independent of pressure (or volume), but the heat content of real gases varies with pressure, hence the need to define the state for the gas (real or ideal) and the pressure. Note that for some thermodynamic databases such as for steam, the reference temperature is 273.15 K (0 °C).
Extensive parameters are properties of the entire system, as contrasted with intensive parameters which can be defined at a single point, such as temperature and pressure. The extensive parameters (except entropy) are generally conserved in some way as long as the system is "insulated" to changes to that parameter from the outside. The truth of ...